Chlorine disappearance in sea-water

A series of chlorination studies were carried out on natural and artificial sea-water. It was determined that both the forward and back titration procedures accurately described the two phases of chlorine losses in sea-water: a rapid initial loss followed by a continuous loss at a sharply reduced rate. The order of adding the iodide and buffer reagents was found to be crucial in affecting the rapid initial loss. The initial loss was found to reach a saturation level that varied widely between natural sea-water samples and appeared to be related to a true organic demand. In contrast, the second phase was difficult to explain. Losses continued over 10 day periods and were pronounced in both natural and artificial sea-water containing bromide. In the absence of bromide, long term losses in artificial sea-water were greatly reduced, indicating that the lost applied chlorine was associated with the bromine chemical system in sea-water. The fate of the lost chlorine was not determined and the untitratable halogen compounds must remain suspect as potential biocides.     

Seasonal variations and mass closure analysis of particulate matter in Hong Kong

The chemical characteristics of ambient particulate matters in urban and rural areas of Hong Kong were determined in this study. A monitoring program starting from November 2000 to February 2001 (winter) and June 2001 to August 2001 (summer) for PM10 and PM2.5 was performed at three monitoring stations in Hong Kong. Twenty-four-hour PM10 and PM2.5 samples were collected once every 6 days at two urban sites, PolyU and KT, and every 12 days at a background site, HT, with Hi-Vol samplers. High concentrations of OC, EC (except in PolyU), water-soluble ions and elements were observed in winter among the three sampling sites for PM10 and PM2.5 fractions. Seasonal variations were significant in background HT. Dilution effect due to the increase in mixing depth and precipitation in summer reduced the concentrations of particulate matters. Long-range transport could contribute to the higher concentrations of particulate matter in the winter. Chemical mass closure calculations were performed for PM10 and PM2.5 observed. Mass closure improved when separate factors (1.4 and 1.9 respectively) were used to convert water-soluble organic carbon (WSOC) and water-insoluble organic carbon (WINSOC) into corresponding organic masses. The urban sites showed high percentages of water-soluble ions in winter and high percentages of carbonaceous species in summer. Better results were obtained for the chemical mass closure analysis in winter than in summer. High temperature and solar radiation in summer increased the rate of the complex photochemical reaction in the atmosphere. Therefore the chemical mass closure analysis would underestimate the volatized species and secondary aerosols during summer.     

Chemical compositions and source identification of PM₂.₅ aerosols for estimation of a diesel source surrogate

Exposure to traffic-related pollution during childhood has been associated with asthma exacerbation, and asthma incidence. The objective of the Cincinnati Childhood Allergy and Air Pollution Study (CCAAPS) is to determine if the development of allergic and respiratory disease is associated with exposure to diesel engine exhaust particles. A detailed receptor model analyses was undertaken by applying positive matrix factorization (PMF) and UNMIX receptor models to two PM_2.5 data sets: one consisting of two carbon fractions and the other of eight temperature-resolved carbon fractions. Based on the source profiles resolved from the analyses, markers of traffic-related air pollution were estimated: the elemental carbon attributed to traffic (ECAT) and elemental carbon attributed to diesel vehicle emission (ECAD).Application of UNMIX to the two data sets generated four source factors: combustion related sulfate, traffic, metal processing and soil/crustal. The PMF application generated six source factors derived from analyzing two carbon fractions and seven factors from temperature-resolved eight carbon fractions. The source factors (with source contribution estimates by mass concentrations in parentheses) are: combustion sulfate (46.8%), vegetative burning (15.8%), secondary sulfate (12.9%), diesel vehicle emission (10.9%), metal processing (7.5%), gasoline vehicle emission (5.6%) and soil/crustal (0.7%). Diesel and gasoline vehicle emission sources were separated using eight temperature-resolved organic and elemental carbon fractions. Application of PMF to both datasets also differentiated the sulfate rich source from the vegetative burning source, which are combined in a single factor by UNMIX modeling. Calculated ECAT and ECAD values at different locations indicated that traffic source impacts depend on factors such as traffic volumes, meteorological parameters, and the mode of vehicle operation apart from the proximity of the sites to highways. The difference in ECAT and ECAD, however, was less than one standard deviation. Thus, a cost benefit consideration should be used when deciding on the benefits of an eight or two carbon approach.     

Structural Insight into the Complex of Ferredoxin and [FeFe] Hydrogenase from Chlamydomonas reinhardtii

The transfer of photosynthetic electrons by the ferredoxin PetF to the [FeFe] hydrogenase HydA1 in the microalga Chlamydomonas reinhardtii is a key step in hydrogen production. Electron delivery requires a specific interaction between PetF and HydA1. However, because of the transient nature of the electron‐transfer complex, a crystal structure remains elusive. Therefore, we performed protein–protein docking based on new experimental data from a solution NMR spectroscopy investigation of native and gallium‐substituted PetF. This provides valuable information about residues crucial for complex formation and electron transfer. The derived complex model might help to pinpoint residue substitution targets for improved hydrogen production.     

On the performance of heterogeneous MANETs

Recent decades have witnessed the birth of major applications of wireless communication technology, further supported by the increasing capabilities of portable devices, low cost and ubiquitous presence. Despite radio technology diversity, a great deal of existing research focuses on a single and isolated wireless technology at a time, where homogeneous elements are identified by IP addresses. This work presents a heterogeneous technology routing (HTR) Framework, targeted towards scenarios where the heterogeneity of devices and networking technologies is present. Our contribution is many fold. It consists of a framework, which encompasses a process for bootstrapping networks, a routing protocol capable of dealing with multiple network interfaces, and a tuning with multipath extensions. We evaluate the performance of the bootstrap, routing and multipath mechanisms by way of simulation and an actual testbed implementation. The multipath evaluation simulates HTR networks with WiMAX, 3GPP LTE and Wi-Fi support. Results show that our proposal can effectively improve the data delivery ratio for ad-hoc networks and that it reduces the end-to-end delay without major impact on network energy consumption. As part of HTR tuning, we investigate next the impacts of tuning the HELLO refresh interval timer on route convergence and its subsequent energy consumption reduction during this phase. We also compare our tuned HTR with the widely used optimized link state routing protocol. Results show that varying the HELLO refresh interval can improve the convergence time and reduce the energy consumption without major impact on network behavior. Our proposal also includes a new distributed address allocation algorithm, namely, the dynamic node configuration protocol (DNCP). This paper conducts a comparative analysis between the Prime, Prophet and the DNCP schemes using static and dynamic topologies in terms of network setup time, energy consumption and control message overhead. Results show that the DNCP had a lower battery power consumption and less control message overhead while it slightly suffers with regard to setup.

     

Evaluation of the effects of two alternative participatory ergonomics intervention strategies for construction companies

To improve the use of ergonomics tools by construction workers, the effect of two guidance strategies – a face-to-face strategy (F2F) and an e-guidance strategy (EG) – of a participatory ergonomics intervention was studied. Twelve construction companies were randomly assigned to the F2F group or the EG group. The primary outcome measure, the percentage of workers using ergonomics tools, and secondary outcome measures – work ability, physical functioning and limitations due to physical problems – were assessed using surveys at baseline and after 6 months. Additionally, a cost-benefit analysis was performed on company level. No differences in primary and secondary outcomes were found with the exception of the use of ergonomics tools to adjust working height (F2F +1%; EG +10%; p?=?.001). Newly-implemented tools were used by 23% (F2F) and 42% (EG) of the workers (p?=?.271). Costs were mainly determined by guidance costs (F2F group) or purchase costs (EG group).

Practitioner Summary: Participatory strategies aim to stimulate behavioural change of stakeholders to increase the use of ergonomics tools. Two guidance strategies – face-to-face or e-mail interventions – among construction companies were studied. Both guidance strategies led to an increase in the use of new ergonomics tools.     

Incorporation of pyridinic and graphitic N to Ni@CNTs: As a competent electrocatalyst for hydrogen evolution reaction

Cheap production of hydrogen (H₂) from eco-friendly routes is preeminent for solving future energy challenges. This study explores the hydrogen evolution reaction (HER) activity of nickel (Ni) nanoparticles and nitrogen doped carbon nanotubes (NiNCNTs), which are fabricated by a cheap and one-step pyrolysis method. The most active catalyst synthesized at 800°C exhibits an overpotential of 0.244 V to reach a current density of 10 mA cm⁻², Tafel slope of 93.3 mV dec⁻¹ and a satisfactory 10 hours stability. Low resistance and large ECSA value of the sample also favor the competent response for HER in alkaline media. The robust HER activity of the catalyst is as a result of the nickel nanoparticles which are the active spots of reaction; while the presence of well-developed nitrogen containing carbon nanotubes with large content of pyridinic and graphitic nitrogen may provide high-electron density and feasible routes for its transportation to deliver an outstanding HER performance.